SECTION 2) HAZARDS IDENTIFICATION
Target Organ Toxicity -Single Exposure (Respiratory Tract Irritation) - Category 3
- Category 2
Eye Irritation - Category 2A
Aerosols Category 1
Acute toxicity, Oral - Category 5
Hazardous Statements - Physical:
- Extremely flammable aerosol
H229 - Pressurised container: May burst if heated
Statements - Health:
H335 - May cause respiratory irritation
H315 - Causes
H319 - Causes serious eye irritation
H303 - May be harmful
Precautionary Statements - General:
P101 - If medical advice
is needed, have product container or label at hand.
P102 - Keep out of reach of children.
P103 - Read label before use.
Precautionary Statements - Prevention:
- Avoid breathing dust/fume/gas/mist/vapors/spray.
P271 - Use only outdoors or in a well-ventilated
SAFETY DATA SHEET
Oct 14, 2015
INDUSTRIAL SUPPLY, INC.
Product ID: SAFETY SHIELD
WEST FOOTHILL BLVD
UPLAND ,CA. 91786
1) CHEMICAL PRODUCT AND SUPPLIER'S IDENTIFICATION
Date Printed: Oct 14, 2015
Supersedes Date: N.A.
Shield Glass Treatment
Information Phone Number:
CHEMTREC US : 1-800-424-9300, INTERNATIONAL CALLS : 1-703-527-3887
Product/Recommended Uses: Glass Treatment
Page 1 of 8
P233 - Keep container tightly closed. P264 - Wash thoroughly after handling.
P280 - Wear protective gloves/protective clothing/eye protection/face protection.
- Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
- Do not spray on an open flame or other ignition source.
P251 - Do not pierce or burn, even after
Precautionary Statements - Response:
P304 + P340 - IF INHALED: Remove
person to fresh air and keep comfortable for breathing.
P312 - Call a POISON CENTER/doctor if you
P302 + P352 - IF ON SKIN: Wash with plenty of water.
- For specific treatment see section 4.
P332 + P313 - If skin irritation occurs: Get medical advice/attention.
P362 + P364 - Take off contaminated clothing. And wash it before reuse.
+ P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing.
P337 + P313 - If eye irritation persists: Get medical advice/attention.
Precautionary Statements - Storage:
P403 + P405 - Store in a well-ventilated
place. Store locked up.
P410 + P412 - Protect from sunlight. Do not expose to temperatures exceeding
50 °C/122 °F.
Precautionary Statements - Disposal:
P501 - Dispose
of contents/container to disposal recycling center. Under RCRA it is the responsibility of the user of the product to determine
at the time of disposal whether the product meets RCRA criteria for hazardous waste. Waste management should be in full compliance
with federal, state and local laws.
SECTION 4) FIRST-AID MEASURES
Remove source of exposure or move person to fresh air and keep comfortable for breathing.
exposed/feel unwell/concerned: Call a POISON CENTER/doctor.
Eliminate all ignition sources if safe
to do so.
Take off contaminated clothing, shoes and leather
goods (e.g. watchbands, belts). Wash with plenty of lukewarm, gently flowing water for a duration of 15-20 minutes. If skin
irritation occurs: Get medical advice/attention. Wash contaminated clothing before re-use.
or concerned: Get medical advice/attention.
of exposure or move person to fresh air. Rinse eyes cautiously with lukewarm, gently flowing water for several minutes, while
holding the eyelids open. Remove contact lenses, if present and easy to do. Continue rinsing for a duration of 15-20 minutes.
Take care not to rinse contaminated water into the unaffected eye or onto the face. If eye irritation persists: Get medical
Immediately call a POISON CENTER/doctor. Do NOT induce vomiting. If
vomiting occurs naturally, lie on your side, in the recovery position. Do not give anything.
5) FIRE-FIGHTING MEASURES
SECTION 3) COMPOSITION / INFORMATION ON INGREDIENTS
CAS Chemical Name % By Weight
0000064-17-5 ETHYL ALCOHOL 41% - 68%
ACETONE 18% - 30%
0000067-63-0 ISOPROPYL ALCOHOL 5% - 11%
Petroleum gases, liquefied, sweetened 3% - 6%
0000124-38-9 CO2 0.1% - 2%
Page 2 of 8
Suitable Extinguishing Media:
Dry chemical, foam, carbon dioxide
is recommended. Water spray is recommended to cool or protect exposed materials or structures. Carbon dioxide can displace
oxygen. Use caution when applying carbon dioxide in confined spaces. Simultaneous use of foam and water on the same surface
is to be avoided as water destroys the foam. Sand or earth may be used for small fires only.
not direct a solid stream of water or foam into hot, burning pools this may results in frothing and increase fire intensity.
Unsuitable Extinguishing Media:
Hazards in Case of Fire:
Contents under pressure. Keep away from ignition sources and open flames.
Exposure of containers to extreme heat and flames can cause them to rupture often with violent force.Product is highly flammable
and forms explosive mixtures with air, oxygen, and all oxidizing agents. Vapors are heavier than air and may travel along
surfaces to remote ignition sources and flash back.
During a fire, irritating and highly toxic gases
may be generated during combustion or decomposition. High temperatures can cause sealed containers to rupture due to
a build up of internal pressures. Cool with water.
DO NOT cut, drill, grind, or weld near
full, partially full, or empty product containers.
Container could potentially burst or be punctured
upon mechanical impact, releasing flammable vapors.
immediate hazard area and keep unauthorized personnel out. Stop spill/release if it can be done safely. Move undamaged containers
from immediate hazard area if it can be done safely. Water spray may be useful in minimizing or dispersing vapors and to protect
personnel. Water may be ineffective but can be used to cool containers exposed to heat or flame. Caution should be exercised
when using water or foam as frothing may occur, especially if sprayed into containers of hot, burning liquid.
of fire debris and contaminated extinguishing water in accordance with official regulations.
Wear protective pressure self-contained breathing apparatus (SCBA) and full
SECTION 6) ACCIDENTAL RELEASE MEASURES
ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).
not touch or walk through spilled material.
Isolate hazard area and keep unnecessary people away.
Remove all possible sources of ignition in the surrounding area. Notify authorities if any exposure to the general public
or the environment occurs or is likely to occur.
If spilled material is cleaned up using a regulated
solvent, the resulting waste mixture may be regulated.
pressure, full-facepiece self-contained breathing apparatus (SCBA), or positive pressure supplied air respirator with escape
SCBA (NIOSH approved). Personal Precautions:
Avoid breathing vapor. Avoid contact with skin, eye
or clothing. ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Do not touch damaged
containers or spilled materials unless wearing appropriate protective clothing. Environmental Precautions:
spill/release if it can be done safely. Prevent spilled material from entering sewers, storm drains, other unauthorized drainage
systems and natural waterways by using sand, earth, or other appropriate barriers. Methods and Materials for Containment and
Cover spills with inert absorbent and place in closed chemical waste containers.
SECTION 7) HANDLING AND STORAGE
hands after use. Do not get in eyes, on skin or on clothing. Do not breathe vapors or mists. Use good personal hygiene practices.
Eating, drinking and smoking in work areas is prohibited. Remove contaminated clothing and protective equipment before entering
Eyewash stations and showers should be available in areas where this material is used
Use only with adequate ventilation
to control air contaminants to their exposure limits. The use of local ventilation is recommended to control emissions near
QUA01201 Page 3 of 8
Storage Room Requirements:
container(s) tightly closed and properly labeled. Store in cool, dry, well-ventilated areas away from heat, direct sunlight,
strong oxidizers and any incompatibilities. Store in approved containers and protect against physical damage. Keep containers
securely sealed when not in use. Indoor storage should meet OSHA standards and appropriate fire codes. Containers that have
been opened must be carefully resealed to prevent leakage. Empty containers retain residue and may be dangerous. Use non-sparking
ventilation systems, approved explosion-proof equipment and intrinsically safe electrical systems in areas where this product
is used and stored.
Do not cut, drill, grind, weld or perform similar operations on or near containers.
Do not pressurize containers to empty them.
Store at temperatures below 120°F.
8) EXPOSURE CONTROLS/PERSONAL PROTECTION
protection with side shields or goggles. Wear indirect-vent, impact and splash resistant goggles when working with liquids.
If additional protection is needed for entire face, use in combination with a face shield. Skin Protection:
of gloves approved to relevant standards made from the following materials may provide suitable chemical protection: PVC,
neoprene or nitrile rubber gloves. Suitability and durability of a glove is dependent on usage, e.g. frequency and duration
of contact, chemical resistance of glove material, glove thickness, dexterity. Always seek advice from glove suppliers. Contaminated
gloves should be replaced. Use of an apron and over- boots of chemically impervious materials such as neoprene or nitrile
rubber is recommended to avoid skin sensitization. The type of protective equipment must be selected according to the concentration
and amount of the dangerous substance at the specific workplace. Launder soiled clothes or properly disposed of contaminated
material, which cannot be decontaminated. Respiratory Protection:
If engineering controls do not
maintain airborne concentrations to a level which is adequate to protect worker, a respiratory protection program that meets
or is equivalent to OSHA 29 CFR 1910.134 and ANSI Z88.2 should be followed. Check with respiratory protective equipment suppliers.
Appropriate Engineering Controls:
Provide exhaust ventilation or other engineering controls to keep
the airborne concentrations of vapors below their respective threshold limit value.
OSHA TWA (ppm)
OSHA TWA (mg/m3)
OSHA STEL (mg/m3)
OSHA Tables (Z1,
OSHA Skin designation
NIOSH TWA (mg/m3)
NIOSH STEL (mg/m3)
ACETONE 1000 2400 1 250 590 CO2 5000 9000 1 5000 9000 30000 54000 ETHYL
ALCOHOL 1000 1900 1 1000 1900 ISOPROPYL ALCOHOL 400 980 1 400 980 500 1225 Petroleum gases, liquefied, sweetened 500 2000
Chemical Name ACGIH TWA (ppm)
ACGIH STEL (ppm)
ACGIH STEL (mg/m3)
ACETONE 500 1188 750 1782 CO2 5000 9000 30000 54000 ETHYL ALCOHOL 1000 ISOPROPYL ALCOHOL 200 400 Petroleum gases, liquefied,
SECTION 9) PHYSICAL AND CHEMICAL PROPERTIES
Density 6.50126 lb/gal
Density VOC 4.70890 lb/gal
QUA01201 Page 4 of 8
Appearance Clear Liquid
Odor Description Alcohol
Water Solubility N.A.
Flash Point Symbol N.A.
Lower Explosion Level N.A.
Explosion Level N.A.
Vapor Pressure N.A.
Vapor Density N.A.
Freezing Point N.A.
Melting Point N.A.
High Boiling Point N.A.
Auto Ignition Temp N.A.
Evaporation Rate N.A.
VOC Composite Partial Pressure N.A.
Actual 564.26737 g/l
VOC Actual 4.70890 lb/gal
% VOC 72.43055%
SECTION 10) STABILITY AND REACTIVITY
is stable at standard temperature and pressure.
Conditions to Avoid:
away from direct sunlight and other sources of ignition. Dropping containers may cause bursting. Hazardous Reactions/Polymerization:
Will not occur
oxidizers, reducers, acids, and alkalis.
Hazardous Decomposition Products:
SECTION 11) TOXICOLOGICAL INFORMATION
Prolonged or repeated contact with this product may dry and/or defat the skin. This product may be harmful
if it is absorbed through the skin.
Causes skin irritation
Eye contact may lead to permanent damage if not treated promptly.
or vapors may irritate the eyes.
Symptoms may include stinging, tearing, redness, swelling, and
blurred vision. Eye contact may lead to permanent damage if not treated promptly.
No Data Available
QUA01201 Page 5 of 8
rat): 30000 ppm (4-hour exposure); cited as 71000 mg/m3 (4-hour exposure) (29) LC50 (male mouse): 18600 ppm (4-hour exposure);
cited as 44000 mg/m3 (4-hour exposure) (29)
LD50 (oral, female rat): 5800 mg/kg (24) LD50 (oral,
mature rat): 6700 mg/kg (cited as 8.5 mL/kg) (31) LD50 (oral, newborn rat): 1750 mg/kg (cited as 2.2 mL/kg) (31) LD50 (oral,
mouse): 3000 mg/kg (32,unconfirmed) LD50 (dermal, rabbit): Greater than 16000 mg/kg cited as 20 mL/kg) (30)
LC50 (mouse): Approximately 21000 ppm (4-hour exposure); cited as 39 g/m3 (4-hour
exposure) (1, unconfirmed)
LD50 (oral, rat): 7060 mg/kg (41); 10600 mg/kg (41); 13660 mg/kg (37)
LD50 (oral, mouse): 3450 mg/kg (1, unconfirmed) LD50 (oral, guinea pig): 5560 mg/kg (37)
LC50 (rat): 17000 ppm (4-hour exposure); cited as 12000 ppm (8-hour exposure)
LD50 (oral, male rat): 4710 mg/kg (cited as 6.0 mL/kg) (19) LD50 (oral, mouse): 3600
mg/kg (20, unconfirmed) LD50 (dermal, rabbit): 12870 mg/kg (cited as 16.4 mL/kg) (14)
Health Effects - Miscellaneous
0000064-17-5 ETHYL ALCOHOL
medical conditions may be aggravated by exposure: liver disease. Tests in some laboratory animals indicate this compound may
have embryotoxic activity. Tests in animals demonstrate reproductive toxicity. Ingestion may cause any of the following: stupor
(central nervous system depression), gastrointestinal irritation. If absorbed through the skin, may be: harmful.
The following medical conditions may be aggravated by exposure: dermatitis, respiratory
disease. Developmental toxicity was seen in rat?s offspring at doses that were maternally toxic. Contact will cause moderate
to severe redness and swelling, itching, tingling sensation, painful burning. May cause injury to the cornea of the eyes.
Prolonged or repeated exposure may cause damage to any of the following organs/systems: liver. Ingestion studies on laboratory
animals showed that very high oral doses caused increased liver and kidney weights.
The following medical conditions may be aggravated by exposure: lung disease, eye disorders,
skin disorders. Overexposure may cause damage to any of the following organs/systems: blood, central nervous system, eyes,
kidneys, liver, respiratory system, skin.
Germ Cell Mutagenicity:
No Data Available
No Data Available
Specific Target Organ Toxicity - Single Exposure:
May cause respiratory irritation
Specific Target Organ Toxicity - Repeated
Prolonged exposure may cause damage to her central nervous system, lungs, skin and eyes.
No Data Available
If inhaled, may cause dizziness, nausea, upper respiratory irritation, drowsiness, mental depression
or narcosis, difficulty in breathing, irregular heart beats.
SECTION 12) ECOLOGICAL INFORMATION
No Data Available
Persistence and Degradability:
No data available.
QUA01201 Page 6 of 8
Mobility in Soil:
Other Adverse Effects:
No data available.
Does not bioaccumulate
91% readily biodegradable, Method:
OECD Test Guideline 301B
SECTION 13) DISPOSAL CONSIDERATIONS
Under RCRA it is the responsibility of the user of the product to determine at the time
of disposal whether the product meets RCRA criteria for hazardous waste. Waste management should be in full compliance with
federal, state and local laws.
Empty Containers retain product residue which may exhibit hazards
of material, therefore do not pressurize, cut, glaze, weld or use for any other purposes. Return drums to reclamation centers
for proper cleaning and reuse.
SECTION 14) TRANSPORT INFORMATION
Ground Transportation: (Continental United States, Canada & Mexico): Limited
Shipping Name: Aerosols, flammable UN/NA #:
1950 Hazard Class: 2.1 Required Placard: Limited Quantity
Marine Pollutant: No data available
We do NOT recommend this product to be shipped via air.
It would need to be repacked by an authorized packing company and the DG would have to be completed by a licensed hazardous
material shipping company.
SECTION 15) REGULATORY INFORMATION
Chemical Name % By Weight Regulation List 0000064-17-5 ETHYL ALCOHOL 41% - 68% SARA312,VOC,TSCA 0000067-64-1 ACETONE 18% -
30% CERCLA,SARA312,VOC_exempt,TSCA,RCRA 0000067-63-0 ISOPROPYL ALCOHOL 5% - 11% SARA312,SARA313,VOC,TSCA 0068476-86-8 Petroleum
gases, liquefied, sweetened 3% - 6% SARA312,VOC,TSCA 0000124-38-9 CO2 0.1% - 2% SARA312,TSCA
16) OTHER INFORMATION
QUA01201 Page 7 of 8
American Conference of Governmental Industrial Hygienists; ANSI- American National Standards Institute; Canadian TDG- Canadian
Transportation of Dangerous Goods; CAS- Chemical Abstract Service; Chemtrec- Chemical Transportation Emergency Center (US);
CHIP- Chemical Hazard Information and Packaging; DSL- Domestic Substances List; EC- Equivalent Concentration; EH40 (UK)- HSE
Guidance Note EH40 Occupational Exposure Limits; EPCRA- Emergency Planning and Community Right-To-Know Act; ESL- Effects screening
levels; HMIS- Hazardous Material Information Service; LC- Lethal Concentration; LD- Lethal Dose; NFPA- National Fire Protection
Association; OEL- Occupational Exposure Limits; OSHA- Occupational Safety and Health Administration, US Department of Labor;
PEL- Permissible Exposure Limit; SARA (Title III)- Superfund Amendments and Reauthorization Act; SARA 313- Superfund Amendments
and Reauthorization Act, Section 313; SCBA- Self-Contained Breathing Apparatus; STEL- Short Term Exposure Limit; TCEQ - Texas
Commission on Environmental Quality; TLV- Threshold Limit Value; TSCA- Toxic Substances Control Act Public Law 94-469; TWA
- Time Weighted Value; US DOT- US Department of Transportation; WHMIS- Workplace Hazardous Materials Information System.
Revision Date: Oct 14, 2015
To the best of our knowledge, the information contained herein
is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the
accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole
responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards
are described herein, we cannot guarantee that these are the only hazards that exist. The above information pertains to this
product as currently formulated, and is based on the information available at this time. Addition of reducers or other
additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are
outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this
QUA01201 Page 8 of 8